Page 22 - 《华中农业大学学报（自然科学版）》2020年第5期
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RSCadvances , ２０１６ , ６ : ５８６１７Ｇ５８６２７． al．Atmos p herichetero g eneousreactionsandtheirenvironmenＧ
[ ３２ ] PARKJY , JANG M , YUZC．Hetero g eneousp hotoＧoxidation taleffects [ J ] ．Environmentalchemistr y , ２０１１ , ３０ ( １ ): ９７Ｇ１１９
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GobiandArizonadust [ J ] ．Environmentalscience&technoloＧ [ ３６ ] GEORGEC , AMMANN M , D ’ ANNAB , etal．Hetero g eneous
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[ ３３ ] HEH , WANGYS , MAQX , etal．MineraldustandNO xp roＧ １１５ ( １０ ): ４２１８Ｇ４２５８．
motetheconversionofSO ２tosulfateinheav yp ollutionda y s [ ３７ ] SETVÍN M , ASCHAUER U , SCHEIBERP , etal．Reactionof
[ J / OL ] ．Scientificre p orts , ２０１５ , ４ : ４１７２ [ ２０２０Ｇ０４Ｇ２９ ] ．htＧ O ２ withsubsurfaceox yg envacancieson TiO ２ anatase ( １０１ )
t p s :// doi．or g / １０．１０３８ / sre p ０４１７２． [ J ] ．Science , ２０１３ , ３４１ ( ６１４９ ): ９８８Ｇ９９１．
[ ３４ ]马庆鑫, 马金珠, 楚碧武, 等 ． 矿质和黑碳颗粒物表面大气非均 [ ３８ ] HEG , MAJ , HE H．Roleofcarbonaceousaerosolsincatal y Ｇ
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X , MAJZ , CHUB W , etal．Current p ro g resstowardsthehetＧ ３８３２．
ero g eneousreactionsonmineraldustandsoot [ J ] ．ChinesesciＧ [ ３９ ]楚碧武, 马庆鑫, 段凤魁, 等 ． 大气“ 霾化学”: 概念提出和研究展
encebulletin , ２０１５ , ６０ ( ２ ): １２２Ｇ１３６ ( inChinesewithEn g lishabＧ 望[ J ] ． 化学进展, ２０２０ , ３２ ( １ ): １Ｇ４．CHU B W , MA Q X , DUＧ
stract ) ． ANFK , etal．Atmos p heric “ HazeChemistr y ”: conce p tandreＧ
[ ３５ ]马金珠, 刘永春, 马庆鑫, 等 ． 大气非均相反应及其环境效应[ J ] ． searchp ros p ects [ J ] ．Pro g ressinchemistr y , ２０２０ , ３２ ( １ ): １Ｇ４ ( in
环境化学, ２０１１ , ３０ ( １ ): ９７Ｇ１１９．MAJZ , LIU YC , MA QX , et ChinesewithEn g lishabstract ) ．
Researchp ro g ressonhetero g eneousreactionsofSO ２onmineral p articles
SHANG Huan , LIU Xiufan , CHEN Na , LIMei q i , CHENZi y ue , AIZhihui , ZHANGLizhi
Colle g eo fChemistr y CentralChinaNormalUniversit y Ke yLaborator yo fPesticide& Chemical
,
/
Biolo gyo f Ministr yo fEducation , Wuhan４３００７９ , China
Abstract Fre q uenteventsofwinterhazeinChinahavecausedvarioushealthissuesinlar g e p o p ulaＧ
tions．Itisbelievedthatthesulfateaerosol p roducedb y aseriesof p h y sicalandchemicalreactionsofSO ２
isanim p ortantcul p ritofhaze g eneration , andthehetero g eneousreactionsofSO ２onmineral p articlesis
p articularl y im p ortant．Therefore , clarif y in g theformationmechanismofsulfateonmineral p articlesisa
ke yscientificp roblemtoanal y zetheformationofhaze．Inthisp a p er , theresearchp ro g ressesaboutthe
t yp icalhetero g eneousreactionsofSO ２onvariousmineral p articleswerereviewed , theeffectsofmultiＧ
p ollutantcoexistences y stem , humidit yandli g htonhetero g eneousreactionsofSO ２ werediscussed , the
futureworkrelatedtohetero g eneousreactionswasalsop ro p osed．This p a p eraimstog ainadee punderＧ
standin gofthemechanismofmineral p articlesp romotin g theformationofsulfateandattem p tstop roＧ
videtheoreticalsu pp ortforeffectivehazecontrol．
;
;
p
Ke y words SO ２ mineral p articles ; sulfate ; hetero g eneousreactions ; hotochemistr y haze
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