基于标准化方法和统计分析法的土壤重金属环境基线值分析比较
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1.湖北省生态环境监测中心站湖北武汉;2.国土资源部稀土稀有稀散矿产重点实验室

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X 53; X820.4

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国家环保公益性科研项目(201509031);2017年土壤污染防治专项湖北省土壤污染风险评估与成因研究项目


Analysis and comparison of environmental baseline values of heavy metals in soils based on standardized methods and statistical methods
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Hubei Environmental Monitoring Center Station

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    摘要:

    :[目的] 通过监测研究区域208个表层土壤重金属Cd、Hg、As、Pb、Cr、Cu、Ni、Zn的含量水平,获得区域表层土壤重金属元素环境基线值,以及区域表层土壤重金属元素环境基线值相对于本底值的变化累积情况,以此来判断区域表层土壤重金属元素受人为活动的扰动程度。[方法] 采用标准化方法和相对累积频率统计方法,计算基于两种方法的重金属环境基线值及偏差,以两种方法获得的重金属环境基线值平均值作为研究区域表层土壤重金属元素环境基线值。[结果] 研究区域监测点位表层土壤重金属Cd、Hg、As、Pb、Cr、Cu、Ni、Zn的含量水平都未超过农用地土壤污染风险筛选值;两种方法获得的区域表层土壤重金属Cd、Hg、As、Pb、Cr、Cu、Ni、Zn的环境基线值平均值分别为0.22 mg/kg、0.09 mg/kg、13.34 mg/kg、30.7 mg/kg、82.0 mg/kg、29.7 mg/kg、38.0 mg/kg、89.1 mg/kg;相对偏差范围在0.5%~12.0%。[结论] 研究区域表层土壤环境质量整体良好,表层土壤重金属Cd、Hg、As、Pb、Cr、Cu、Ni、Zn环境基线值相对于本底值有不同程度的增大,但变化率都小于50%,增加幅度不显著;其中,Cd的累计指数评价等级达到轻度累积,其它重金属元素为无明显累积,说明研究区域表层土壤重金属元素已经受到一定程度的人为因素干扰,影响程度较小。

    Abstract:

    Abstract:[Objectives] The content levels of heavy metals Cd, Hg, As, Pb, Cr, Cu, Ni and Zn in 208 surface soils in the study area were detected. The environmental baseline value of heavy metal elements and the accumulation of changes relative to background values were obtained in regional surface soil. Based on this, the disturbance degree of heavy metal elements in regional surface soil by human activities can be judged. [Methods] Standardized method and relative cumulative percentage statistical method were used to calculate the environmental baseline value and deviation of heavy metals in regional surface soil. The average environmental baseline values obtained by these two methods were taken as the environmental baseline values of heavy metals in the surface soil of the study area. [Results] The content levels of heavy metals Cd, Hg, As, Pb, Cr, Cu, Ni and Zn in the surface soil of the monitoring points in the study area were not exceed the risk screening values for soil contamination of agricultural land. The environmental baseline values of heavy metals Cd, Hg, As, Pb, Cr, Cu, Ni and Zn obtained by these two methods were 0.22 mg/kg, 0.09 mg/kg, 13.34 mg/kg, 30.7 mg/kg, 82.0 mg/kg, 29.7 mg/kg, 38.0 mg/kg and 89.1 mg/kg respectively. The relative deviation ranged from 0.5% to 12.0%. [Conclusions] The environmental quality was generally good of regional surface soil. Compared with the background value, the environmental baseline value increased in different degrees of heavy metals Cd、Hg、As、Pb、Cr、Cu、Ni、Zn in regional surface soil, but the change rate was less than 50%, and the increase was not significant. Among them, the cumulative index evaluation grade of Cd reached slight accumulation, while other heavy metals elements had no obvious accumulation. This shows that heavy metal elements in the surface soil of the study area have been disturbed by human factors to a certain extent, and the influence degree was slight.

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  • 收稿日期:2020-06-22
  • 最后修改日期:2020-07-16
  • 录用日期:2020-07-27
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